Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds.
نویسندگان
چکیده
A low-coordinate iron(ii) complex (CztBu(PztBu)2)Fe[N(SiMe3)2], 1 bearing an NNN-pincer ligand was prepared and fully characterized. Intramolecular C-H activation on the 5-position of a pyrazole at elevated temperatures was observed. Complex 1 was found to be an efficient and chemoselective pre-catalyst for the hydrosilylation of organo carbonyl substrates.
منابع مشابه
Recent developments of iron pincer complexes for catalytic applications
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ورودعنوان ژورنال:
- Dalton transactions
دوره 47 10 شماره
صفحات -
تاریخ انتشار 2018